trans-3-(3,4-Dimeth­oxy­phen­yl)-2-(4-nitro­phen­yl)prop-2-ene­nitrile

نویسندگان

  • Abdullah M. Asiri
  • Salman A. Khan
  • Kong Wai Tan
  • Seik Weng Ng
چکیده

The asymmetric unit of the title compound, C(17)H(14)N(2)O(4), contains two independent mol-ecules in which the benzene rings are in a trans arrangement with respect to the C=C double bond and the rings are inclined by 4.3 (1) and 22.1 (1)° with respect to each other.

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منابع مشابه

(E)-1-(3-Bromo­phen­yl)-3-(3,4-dimeth­oxy­phen­yl)prop-2-en-1-one

The mol-ecular structure of the title compound, C(17)H(15)BrO(3), consists of a bromo-phenyl and a 3,4-dimeth-oxy-phenyl group linked through a prop-2-en-1-one spacer. The C=C double bond displays an E conformation, while the carbonyl group shows an S-cis conformation relative to the double bond.

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(E)-3-(2,4-Dimeth­oxy­phen­yl)-1-(3,4-dimeth­oxy­phen­yl)prop-2-en-1-one

The title compound, C(19)H(20)O(5), is approximately planar; the dihedral angle between the benzene rings is 3.82 (8)°, and the central propenone C(=O)-C=C plane makes dihedral angles of 1.95 (10) and 3.17 (11)° with the two benzene rings. In the crystal structure, intra- and inter-molecular C-H⋯O hydrogen bonds are observed.

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(E)-3-(3,4-Dimeth­oxy­phen­yl)-1-(2-hy­droxy­phen­yl)prop-2-en-1-one

In the title compound, C(17)H(16)O(4), the dihedral angle between the mean planes of the hy-droxy-phenyl and dimeth-oxy-phenyl rings is 5.9 (6)°. The mean plane of the prop-2-en-1-one group makes dihedral angles of 3.6 (0) and 2.6 (7)° with the hy-droxy-phenyl and dimeth-oxy-phenyl rings, respectively. An intra-molecular O-H⋯O hydrogen bond occurs. The crystal packing is stabilized by weak inte...

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(E)-1-(3,4-Dimeth­oxy­phen­yl)-3-[4-(methyl­sulfan­yl)phen­yl]prop-2-en-1-one

In the title compound, C(18)H(18)O(3)S, the C=C double bond exists in an E configuration and the dihedral angle between the two benzene rings is 11.74 (8)°. In the crystal, mol-ecules are linked into a three-dimensional network by C-H⋯O hydrogen bonds. The crystal structure is also stabilized by weak C-H⋯π inter-actions.

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(2E)-1-(2,5-Dimeth­oxy­phen­yl)-3-(3-nitro­phen­yl)prop-2-en-1-one

In the title compound, C(17)H(15)NO(5), an intra-molecular C-H⋯O hydrogen bond generates an S(6) ring motif. The benzene rings form a dihedral angle of 6.45 (7)° with each other. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R(2) (2)(8) loops. Adjacent dimers are further connected by C-H⋯O hydrogen bonds into an infinite chain along the [011] direction.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010